|
|
L-phenylalanine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N-hydroxy-L-phenylalanine + oxidized_[NADPH-hemoprotein_reductase] + H2O + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-12066
|
|
|
|
N-hydroxy-L-phenylalanine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N,N-dihydroxy-L-phenylalanine + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-12067
|
|
|
|
(Z)-1-(L-cysteinyglycin-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O <=> phenylacetothiohydroximate + L-seryl-glycine + H+
|
4.4.1.M2
|
–
|
| |
MetaCyc:
RXN-11436
|
|
|
|
UDP-glucose + phenylacetothiohydroximate <=> desulfoglucotropaeolin + UDP
|
2.4.1.195
N-hydroxythioamide S-beta-glucosyltransferase
|
–
|
| |
BRENDA:
BR48049
KEGG:
R03213
MetaCyc:
2.4.1.195-RXN
SABIO-RK:
3040
|
|
|
|
S-(Phenylacetothiohydroximoyl)-L-cysteine + H2O <=> phenylacetothiohydroximate + pyruvate + NH3 + H+
|
4.4.1
4.4.1.13
cysteine-S-conjugate beta-lyase
|
–
–
|
| |
KEGG:
R08654
MetaCyc:
RXN-8054
|
|
|
|
3''-phosphoadenylyl-sulfate + desulfoglucotropaeolin <=> adenosine_3,5''-bisphosphate + benzylglucosinolate + H+
|
2.8.2.24
aromatic desulfoglucosinolate sulfotransferase
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
–
|
| |
BRENDA:
BR47919;
BS358758
KEGG:
R03214
MetaCyc:
RXN-4606
|
|
|
|
N,N-dihydroxy-L-phenylalanine + H+ <=> (E)-phenylacetaldoxime + CO2 + H2O
|
1.14.14.40
phenylalanine N-monooxygenase
|
–
|
| |
BRENDA:
BR49592
KEGG:
R09581
MetaCyc:
RXN-12068
|
|
|
|
(Z)-1-(L-cysteinyglycin-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O <=> S-(Phenylacetothiohydroximoyl)-L-cysteine + glycine
|
3.4.13.23
cysteinylglycine-S-conjugate dipeptidase
|
–
|
| |
MetaCyc:
RXN-19591
|
|
|
|
(E)-phenylacetaldoxime + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 1-aci-nitro-2-phenylethane + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11412
|
|
|
|
1-aci-nitro-2-phenylethane + glutathione <=> S-[(Z)-N-hydroxy(phenyl)acetimidoyl]-L-glutathione + H2O
|
1.14.14.45
aromatic aldoxime N-monooxygenase
|
–
|
| |
BRENDA:
BR52041
KEGG:
R11739
MetaCyc:
RXN-11420
|
|
|
|
S-[(Z)-N-hydroxy(phenyl)acetimidoyl]-L-glutathione + H2O <=> (Z)-1-(L-cysteinyglycin-S-yl)-N-hydroxy-2-phenylethan-1-imine + L-glutamate
|
3.4.19.16
glucosinolate gamma-glutamyl hydrolase
|
–
|
| |
BRENDA:
BR52190
KEGG:
R11795
MetaCyc:
RXN-11428
|
|
